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Main positions:Director, High Performance Computing Platform, PKU
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Lei Yian

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Education Level: Postgraduate (Doctoral)

Administrative Position: Associate Professor

Alma Mater: Peking University

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The Puzzle of Spin–Orbit Coupling
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The Puzzle of Spin–Orbit Coupling

In traditional quantum mechanics, spin is treated as an “inherently quantum” quantity with no classical counterpart, while orbital angular momentum is regarded as a physical angular momentum in real space. This leads to a profound conceptual difficulty: how can something that “has no physical substance” couple directly to a genuine physical quantity?

1. Textbook Consistency and the “Explanatory Void”

In conventional (instrumentalist) quantum theory, this issue is typically “swept under the rug” through technical formalism:

  • Formally, both the spin operator 𝑆^S^ and the orbital angular momentum operator 𝐿^L^ satisfy the same 𝑠𝑢(2)su(2) algebra:

[𝐿^𝑖,𝐿^𝑗]=𝑖ℏ𝜖𝑖𝑗𝑘𝐿^𝑘,[𝑆^𝑖,𝑆^𝑗]=𝑖ℏ𝜖𝑖𝑗𝑘𝑆^𝑘.[L^i,L^j]=iϵijkL^k,[S^i,S^j]=iϵijkS^k.

The total angular momentum 𝐽^=𝐿^+𝑆^J^=L^+S^ also obeys this algebra.

  • The Hamiltonian includes a spin–orbit coupling term:

𝐻SO=𝜉(𝑟) 𝐿^⋅𝑆^,HSO=ξ(r)L^S^,

where 𝜉(𝑟)ξ(r) arises from relativistic corrections (e.g., Thomas precession).

  • At the spectroscopic level, this yields energy shifts:

𝑗=𝑙±12,𝐸𝑛𝑙𝑗 matches experimental fine structure perfectly.j=l±21,Enlj matches experimental fine structure perfectly.

Numerically, everything works flawlessly.

Yet conceptually, the issue is evaded:

  • 𝐿^L^ retains some vestige of spatial intuition—it corresponds to motion in real space.

  • 𝑆^S^ , however, is declared an “intrinsic quantum number with no classical analogue,” and one is explicitly discouraged from asking “what is actually rotating?”

Nevertheless, these two quantities are coupled via 𝐿^⋅𝑆^L^S^ , mathematically treated as if they were two ordinary three-dimensional vectors.

This raises a critical question:

If 𝐿L represents a real physical angular momentum in space, while 𝑆S is proclaimed to be an abstract “thing without substance,” then the coupling term 𝐿⋅𝑆LS lacks any coherent physical picture.
A genuine physical quantity cannot meaningfully interact with a “non-entity.”

The standard response is essentially: “Don’t ask for a picture—just calculate.”
This is precisely what I critique as the typical practice of substituting representation for ontology.

2. The Physical Origin: Coupling as “Angular Momentum → Magnetic Field → Magnetic Moment”

If we trace the coupling back to its physical derivation, the picture becomes much clearer:

  • In the electron’s rest frame, the orbiting nucleus generates an effective magnetic field 𝐵effBeff .

  • The electron possesses an intrinsic magnetic moment 𝜇μ , leading to an interaction energy:

𝐻𝜇𝐵=−𝜇⋅𝐵eff.HμB=μBeff.

  • In the Pauli or Dirac framework, the magnetic moment operator is written as:

𝜇^=−𝑔𝑒2𝑚𝑆^,μ^=g2meS^,

where 𝑔g is the g-factor. Here, 𝑆^S^ serves as an algebraic device to encode the direction and magnitude of the magnetic moment within an 𝑠𝑢(2)su(2) operator.

  • Meanwhile, 𝐵effBeff is proportional to 𝐿L , since it arises from the electron’s orbital motion in the Coulomb field.

Combining these gives:

𝐻SO∝𝐿^⋅𝑆^.HSOL^S^.

Thus, physically, spin–orbit coupling is nothing more than:

the interaction between an effective magnetic field (produced by orbital motion) and an intrinsic magnetic moment.

The spin operator 𝑆^S^ is merely a convenient algebraic proxy for the magnetic moment’s orientation.

Now, if we interpret 𝜇μ as the magnetic moment of a real field vortex (e.g., a circulating current in the electron’s internal structure), and 𝐵effBeff as the real magnetic field generated by orbital motion, then spin–orbit coupling is simply a classical-like magnetic interaction—with no mysterious “non-classical” element whatsoever.

The real problem lies in traditional quantum theory’s abandonment of ontological imagery: it discards the physical origin and retains only the symbolic representation.

  • 𝜇μ is no longer seen as arising from a real current loop, but merely as a linear image of 𝑆^S^ .

  • 𝑆^S^ is abstracted into an “intrinsic degree of freedom with no classical analogue,” and the question “what rotates?” is forbidden.

Consequently, what was originally a clear magnetic dipole–field interaction gets reinterpreted as a mysterious coupling between an abstract internal label and a real orbital angular momentum.

If we refuse to acknowledge that spin corresponds to a real magnetic moment and internal field rotation—and instead treat it as a mere abstract two-valued label—then spin–orbit coupling becomes physically unintelligible.

3. Naturalization of Spin–Orbit Coupling in Natural Quantum Theory (NQT)

In the NQT framework, this puzzle dissolves into clarity, because:

All Angular Momenta Are Physical

Both “orbital” and “spin” angular momenta correspond, at the ontological level, to integrals of real field angular momentum density:

𝐿=∫𝑑3𝑥 𝑟×𝑝orb(𝑥),𝑆ont=∫𝑑3𝑥 ℓint(𝑥),L=d3xr×porb(x),Sont=d3xint(x),

where 𝑝orbporb is the momentum density associated with center-of-mass motion, and ℓintint is the internal angular momentum density of the electron’s vortex structure. The total angular momentum is simply:

𝐽=𝐿+𝑆ont.J=L+Sont.

This is an axiomatic principle in NQT.

Magnetic Moment Arises from Real Currents

The electron’s magnetic moment is not an abstract property but the result of internal electromagnetic vortex currents:

𝜇ont=∫𝑑3𝑥 12𝑟×𝐽charge(𝑥),μont=d3x21r×Jcharge(x),

and it bears a definite structural relationship to 𝑆ontSont (modified by Thomas precession).

Under this ontological picture, the story of spin–orbit coupling becomes transparent:

  • Orbital angular momentum 𝐿L : angular momentum of the electron’s center-of-mass motion around the nucleus.

  • Ontological spin 𝑆ontSont : real angular momentum of the internal field vortex.

  • The orbital motion generates an effective magnetic field 𝐵eff(𝐿)Beff(L) in the electron’s rest frame.

  • The internal vortex’s magnetic moment 𝜇ont(𝑆ont)μont(Sont) couples to this field.

At the ontological level, this is purely a magnetic moment–field interaction—no abstraction, no mystery.

Only after projecting onto the spectroscopic representation (introducing the spin operator 𝑆^S^ ) and accounting for Thomas precession does this interaction take the familiar form:

𝐻SO=𝜉(𝑟) 𝐿^⋅𝑆^,HSO=ξ(r)L^S^,

with coefficients matching fine structure experiments.

Thus, we can now critique the traditional view:

“If spin is deliberately stripped of physical content and reduced to an abstract 𝑠𝑢(2)su(2) label, then spin–orbit coupling—as a ‘mysterious interaction between an abstract internal quantity and real orbital motion’—is indeed inexplicable. But in reality, what couples are the real magnetic field produced by orbital motion and the real magnetic moment of the electron’s internal vortex. The expression 𝐿⋅𝑆LS is merely the spectroscopic representation of this underlying magnetic interaction.”

4. Conclusion

In spin–orbit coupling, if spin is interpreted as a purely abstract, “non-classical” intrinsic quantity, then its coupling to the physical orbital angular momentum 𝐿L via 𝐿⋅𝑆LS loses all physical imagery, leaving only an algebraic rule that “works but cannot be understood.”

From the ontological perspective of Natural Quantum Theory, this is unacceptable. Spin is first and foremost the real angular momentum of the electron’s internal field vortex, carrying a real magnetic moment. Spin–orbit coupling is physically just the interaction between the effective magnetic field generated by orbital motion and this intrinsic magnetic moment. The operator form 𝐿^⋅𝑆^L^S^ is merely its representation in the spectroscopic (quantum-number) framework.

To erase this physical grounding and retain only abstract operators is yet another source of the mystification that plagues conventional quantum mechanics.