简介

先进碳材料与能源化学课题组(GRE@C)


高鑫,北京大学助理教授,研究员,博士生导师,入选国家级人才计划(青年项目)。2018年博士毕业于北京大学化学与分子工程学院(导师:张锦 院士),2019-2023年在美国斯坦福大学材料系从事博士后研究(合作导师:Prof. Yi Cui),2023年加入北京大学材料科学与工程学院(张锦院士团队)。在Nature Nanotechnology, Science Advances, Advanced Materials, Chemical Society Reviews, Journal of the American Chemical Society, Proceedings of the National Academy of Sciences 等杂志发表论文40余篇,总引用4000余次。曾获北京大学优秀博士论文,博士研究生国家奖学金、北京大学校长奖学金等奖励,出版学术专著《石墨双炔薄膜的合成方法与应用探索》。

本课题组主要围绕碳基纳米材料的结构控制制备与能源化学开展创新性研究,主要研究方向包括(1)碳基纤维材料的控制制备与结构功能一体化;(2)新型碳材料石墨炔的控制制备与应用探索;(3)高能量密度二次电池的设计与开发。


已发表工作

  1. Y. Sun, X. Gao*, T. Ma, and J. Zhang*. High-performance Na-S batteries enabled by a chemical and spatial dual-confinement strategy. Matter 2024, 7, 1920-1924.

  2. Z. Zhang#, X. Feng#, Z. Zhang, L. Chen, W. Liu, L. Tong*, X. Gao*, and J. Zhang*. Graphdiyne Enabled Nitrogen Vacancy Formation in Copper Nitridefor Efficient Ammonia Synthesis. J. Am. Chem. Soc. 2024, 146, 14898-14904.

  3. Z. Hu#, X. Sun#, X. Zhang, X. Jia, X. Feng, M. Cui, E. Gao, L. Qian*, X. Gao*, and J. Zhang*. Kinetic modulation of carbon nanotube growth in direct spinning for high-strength carbon nanotube fibers. J. Am. Chem. Soc. 2024, 146, 11432. 

  4. X. Gao#, X. Zheng#*, Y. Ye#, H. K. Lee, P. Zhang, A. Cui, X. Xiao, Y. Yang, Y. Cui*. Lithiophilic Hydrogen-Substituted Graphdiyne Aerogels with Ionically Conductive Channels for High-Performance Lithium Metal Batteries. Nano Lett. 2024, 24, 10, 3044.

  5. S. C. Kim#Xin Gao#, S. Liao, H. Su, Y. Chen, W. Zhang, L. C. Greenburg, J. Pan, X. Zheng, Y. Ye, M. S. Kim, P. Sayavong, A. Brest, J. Qin*, Z. Bao*, Y. Cui*. Solvation-property relationship of lithium-sulphur battery electrolytes. Nat. Commun. 2024, 15, 1268. 

  6. X. Gao#, Z. Yu#, J. Wang, X. Zheng, Y. Ye, H. Gong, X. Xiao, Y. Yang, Y. Chen, S. E. Bone, L. C. Greenburg, P. Zhang, H. Su, J. Affeld, Z. Bao*, Y. Cui*, Electrolytes with moderate lithium polysulfide solubility for high-performance long-calendar-life lithium–sulfur batteries. Proc. Natl. Acad. Sci. 2023, 120, e2301260120.

  7. X. Zheng#, X. Gao#, R. A. Vilá, Y. Jiang, J. Wang, R. Xu, R. Zhang, X. Xiao, P. Zhang, L. C. Greenburg, Y. Yang, H. L. Xin, X. Zheng, Y. Cui*. Hydrogen-substituted graphdiyne-assisted ultrafast sparking synthesis of metastable nanomaterials. Nat. Nanotechnol. 2023, 18, 153-159.

  8. X. Gao, X. Zheng, Y. Tsao, P. Zhang, X. Xiao, Y. Ye, J. Li, Y. Yang, R. Xu, Z. Bao, Y. Cui*. All-solid-state lithium–sulfur batteries enhanced by redox mediators. J. Am. Chem. Soc. 2021, 143, 18188-18195.

  9. X. Gao, X. Zheng, J. Wang, Z. Zhang, X. Xiao, J. Wan, Y. Ye, L. Chou, H. K. Lee, J. Wang, R. A. Vilá, Y. Yang, P. Zhang, L. Wang, Y. Cui*. Incorporating the nanoscale encapsulation concept from liquid electrolytes into solid-state lithium–sulfur batteries. Nano Lett. 2020, 20, 5496-5503.

  10. X. Gao, H. Liu, D. Wang, J. Zhang*. Graphdiyne: synthesis, properties, and applications. Chem. Soc. Rev. 2019, 48, 908-936.

  11. X. Gao#, Y. Zhu#, Y. Ding, J. Zhou, S. Zhang, C. Yin, F. Ding, S. Zhang, X. Yi, J. Wang, L. Tong*, Y. Han*, Z. Liu*, J. Zhang*. Ultrathin graphdiyne film on graphene through solution-phase van der Waals epitaxy. Sci. Adv. 2018, 4, eaat6378.

  12. X. Gao#, J. Li#, R. Du, J. Zhou, M. Huang, R. Liu, J. Li, Z. Xie, L. Wu*, Z. Liu*, J. Zhang*. Direct synthesis of graphdiyne nanowalls on arbitrary substrates and its application for photoelectrochemical water splitting cell. Adv. Mater. 2017, 1605308.

  13. X. Gao#, H. Ren#, J. Zhou, R. Du, C. Yin, R. Liu, H. Peng, L. Tong*, Z. Liu*, J. Zhang*. Synthesis of hierarchical graphdiyne-based architecture for efficient solar steam generation. Chem. Mater. 2017, 29, 5777-5781.

  14. J. Li#, X. Gao#, X. Jiang, X. Li, Z. Liu, J. Zhang*, C. Tung, and L. Wu*. Graphdiyne: A Promising Catalyst–Support To Stabilize Cobalt Nanoparticles for Oxygen Evolution. ACS Catal. 2017, 28, 5209-5213.

  15. X. Gao, J. Zhou , R. Du , Z. Xie , S. Deng , R. Liu, Z. Liu*, J. Zhang*. Robust Superhydrophobic Foam: A Graphdiyne-BasedHierarchical Architecture for Oil/Water Separation. Adv. Mater. 2016, 28, 168-173.

  16. J. Li#, X. Gao#, B. Liu, Q. Feng, X. Li, M. Huang, Z. Liu, J. Zhang*, C. Tung, Li. Wu*. Graphdiyne: A metal-free material as hole transfer layer to fabricate quantum dot-sensitized photocathodes for hydrogen production. J. Am. Chem. Soc. 2016, 138, 3954-3957.

  17. Y. Ye, R. Xu, W. Huang, H. Ai, W. Zhang, J. O. Affeld, A. Cui, F. Liu, X. Gao, Z. Chen, T. Li, X. Xiao, Z. Zhang, Y. Peng, R. A. Vila, Y. Wu, S. T. Oyakhire, H. Kuwajima, Y. Suzuki, R. Matsumoto, Y. Masuda, T. Yuuki, Y. Nakayama, Y. Cui*. Quadruple the rate capability of high-energy batteries through a porous current collector design. Nat. Energy 2024, accepted.

  18. X. Zheng, S. Paul, L. Moghimi, Y. Wang, R. A. Vilá, F. Zhang, X. Gao, J. Deng, Y. Jiang, X. Xiao, C. Wu, L. C. Greenburg, Y. Yang, Y. Cui, A. Vailionis, I. Kuzmenko, J. Llavsky, Y. Yin, Y. Cui, L. Dresselhaus-Marais*. Proc. Nat. Acad. Sci. 2023, 120, e2305097120.

  19. H. Gong, D. U. Patino, J. Ilavsky, I. Kuzmenko, A. E. Peña-Alcántara, C. Zhu, A. H. Coffey, L. Michalek, A. Elabd, X. Gao, S. Chen, C. Xu, H. Yan, Y. Jiang, W. Wang, Y. Peng, Y. Zeng, H. Lyu, H. Moon, Z. Bao*. Tunable 1D and 2D Polyacrylonitrile Nanosheet Superstructures. ACS Nano 2023, 17, 18392.

  20. Y. Peng, J. Lai, X. Xiao, W. Jin, J. Zhou, Y. Yang, X. Gao, J. Tang, L. Fan, S. Fan, Z. Bao, Y. Cui*. Colorful low-emissivity paints for space heating and cooling energy savings. Proc. Nat. Acad. Sci. 2023, 120, e2300856120.

  21. L. C. Greenburg, X. Gao, P. Zhang, X. Zheng, J. Wang, R. A. Vilá, Y. Cui*. Ni Anchored to Hydrogen-Substituted Graphdiyne for Lithium Sulfide Cathodes in Lithium–Sulfur Batteries. Nano Lett. 2023, 23, 5967.

  22. Z. Huang, J. Lai, S. Liao, Z. Yu, Y. Chen, W. Yu, H. Gong, X. Gao, Y. Yang, J. Qin, Y. Cui*, Z. Bao*. A salt-philic, solvent-phobic interfacial coating design for lithium metal electrodes. Nat. Energy 2023, 8, 577.

  23. S. C. Kim, S. T. Oyakhire, C. Athanitis, J. Wang, Z. Zhang, W. Zhang, D. T. Boyle, M. S. Kim, Z. Yu, X. Gao, T. Sogade, E. Wu, J. Qin*, Z. Bao*, S. F. Bent*, Y. Cui*. Data-driven electrolyte design for lithium metal anodes. Proc. Nat. Acad. Sci. 2023, 120, e2214357120.

  24. Z. Huang, J. Lai, X. Kong, I. Rajkovic, X. Xiao, H. Celik, H. Yan, H. Gong, P. E. Rudnicki, Y. Lin, Y. Ye, Yanbin Li, Y. Chen, X. Gao, Y. Jiang, S. Choudhury, J. Qin, J. B-H Tok, Y. Cui*, Z. Bao*. A solvent-anchored non-flammable electrolyte. Matter 2023, 6, 445.

  25. Y. Ye, W. Huang, R. Xu, X. Xiao, W. Zhang, H. Chen, J. Wan, F. Liu, H. K. Lee, J. Xu, Z. Zhang, Y. Peng, H. Wang, X. Gao, Y. Wu, G. Zhou, Y. Cui*. Cold-Starting All-Solid-State Batteries from Room Temperature by Thermally Modulated Current Collector in Sub-Minute. Adv. Mater. 2022, 34, 2202848.

  26. H. K. Lee, W. Huang, Y. Ye, J. Xu, Y. Peng, T. Wu, A. Yang, L. Chou, X. Xiao, X. Gao, F. Liu, H. Wang, B. Liu, J. Wang, Y. Cui*. Sensitive, portable heavy-metal-ion detection by the sulfidation method on a superhydrophobic concentrator (SPOT). One Earth 2021, 4, 756.

  27. L. Chou, Y. Ye, H. K. Lee, W. Huang, R. Xu, X. Gao, R. Chen, F. Wu, C. Tsung, Y. Cui*. Electrolyte-resistant dual materials for the synergistic safety enhancement of lithium-ion batteries. Nano Lett. 2021, 21, 5, 2074.

  28. J. Li, X. Gao, L. Zhu, M. N. Ghazzal*, J. Zhang*, C. Tung, L. Wu*. Graphdiyne for crucial gas involved catalytic reactions in energy conversion applications. Energy Environ. Sci. 2020, 13, 1326. (Review Article)

  29. Y. Ye, L. Chou, Y. Liu, H. Wang, H. K. Lee, W. Huang, J. Wan, K. Liu, G. Zhou, Y. Yang, A. Yang, X. Xiao, X. Gao, D. T. Boyle, H. Chen, W. Zhang, S. C. Kim, Y. Cui*. Ultralight and fire-extinguishing current collectors for high-energy and high-safety lithium-ion batteries. Nat. Energy 2020, 5, 786.

  30. J. Li, X. Gao, Z. Li, J. Wang, L. Zhu, C. Yin, Y. Wang, X. Li, Z. Liu, J. Zhang*, C. Tung, L. Wu*. Superhydrophilic Graphdiyne: Superhydrophilic Graphdiyne Accelerates Interfacial Mass/Electron Transportation to Boost Electrocatalytic and Photoelectrocatalytic Water Oxidation. Adv. Funct. Mater. 2019, 29, 1808079.

  31. H. Ren, L. Zheng, G. Wang, X. Gao, Z. Tan, J. Shan, L. Cui, K. Li, M. Jian, L. Zhu, Y. Zhang, H. Peng*, D. Wei*, and Zh. Liu*. Transfer-Medium-Free Nanofiber-Reinforced Graphene Film and Applications in Wearable Transparent Pressure Sensors. ACS Nano 2019, 13, 5, 5541.

  32. J. Li, Y. Xiong, Z. Xie, X. Gao, J. Zhou, C. Yin, L. Tong, C. Chen*, Z. Liu*, and J. Zhang*. Template Synthesis of an Ultrathin β-Graphdiyne-Like Film Using the Eglinton Coupling Reaction. ACS Appl. Mater. Interfaces 2019, 11, 3, 2734.

  33. J. Li, J. Xu, Z. Xie, X. Gao, J. Zhou, Y. Xiong, C. Chen*, J. Zhang*, and Z. Liu*. Diatomite-Templated Synthesis of Freestanding 3D Graphdiyne for Energy Storage and Catalysis Application. Adv. Mater. 2018, 30, 1800548.

  34. J. Zhou, Z. Xie, R. Liu, X. Gao, J. Li, Y. Xiong, L. Tong, J. Zhang*, and Z. Liu*. Synthesis of Ultrathin Graphdiyne Film Using a Surface Template. ACS Appl. Mater. Interfaces 2018, 11, 2632.

  35. R. Liu, X. Gao, J. Zhou, H. Xu, Z. Li, S. Zhang, Z. Xie, J. Zhang*, and Z. Liu*. Chemical vapor deposition growth of linked carbon monolayers with acetylenic scaffoldings on silver foil. Adv. Mater. 2017, 29, 1604665.

  36. R. Liu, J. Zhou, X. Gao, J. Li, Z. Xie, Z. Li, S. Zhang, L. Tong*, J. Zhang*, and Z. Liu*. Graphdiyne Filter for Decontaminating Lead-Ion-Polluted Water. Adv. Electron. Mater. 2017, 1700122.

  37. F. Zhang, C. Yang, X. Gao, S. Chen, Y. Hu, H. Guan, Y. Ma, J. Zhang, H. Zhou*, and L. Qi*. SnO2@PANI Core−Shell Nanorod Arrays on 3D Graphite Foam: A High-Performance Integrated Electrode for Lithium-Ion Batteries. ACS Appl. Mater. Interfaces 2017, 9, 9620.

  38. Z. Zheng, H. Fang, D. Liu, Z. Tan, X. Gao, W. Hu, H. Peng, L. Tong, W. Hu, J. Zhang*. Non-Local Response in Infrared Detector with Semiconducting Carbon Nanotubes and Graphdiyne. Adv. Sci. 2017, 4,1700472.

  39. J. Li†, Z. Xie†, X. Yan, Z. Li, Q. Huang, S. Zhang, J. Zhou, R. Liu, X. Gao, C. Chen, L. Tong*, J. Zhang*, and Z. Liu*. Architecture of β-graphdiyne contained thin film using modified glaser-hay coupling reaction for enhanced photocatalytic property of TiO₂. Adv. Mater. 2017, 29, 1700421.

  40. R. Du, Q. Feng, H. Ren, Q. Zhao, X. Gao, J. Zhang*. Hybrid-dimensional magnetic microstructure based 3D substrates for remote controllable and ultrafast water remediation. J. Mater. Chem. A 2016, 4, 938.

  41. R. Du, Q. Zhao, P. Li, H. Ren, X. Gao, J. Zhang*. Ultrathermostable, magnetic-driven, and superhydrophobic quartz fibers for water remediation. ACS Appl. Mater. Interfaces 2016, 8, 1025.

  42. J. Zhou, X. Gao, R. Liu, Z. Xie, J. Yang, S. Zhang, G. Zhang, H. Liu, Y. Li, J. Zhang*, and Z. Liu*. Synthesis of graphdiyne nanowalls using acetylenic coupling reaction. J. Am. Chem. Soc. 2015, 137, 7596.

  43. R. Du, X. Gao, Q. Feng, Q. Zhao, P. Li, S. Deng, L. Shi, J. Zhang*. Microscopic dimensions engineering: Stepwise manipulation of the surface wettability on 3D substrates for oil/water separation. Adv. Mater. 2015, 28, 936.

  44. Y. Du*, X. Gao, X. Ye, Z. Zheng, Q. Feng, C. Wang*, K. Wu*. Composition and architecture-engineered Au–SnO2/GNs-SWCNTs. Sensors and Actuators B 2014, 203, 926.


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